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Acetyl transfer reaction in catechol acetate malonate. Model for the biosynthesis of polyketides and fatty acids

โœ Scribed by Scott, A. Ian; Wiesner, C. J.; Yoo, S.; Chung, Sung-Kee


Book ID
126941968
Publisher
American Chemical Society
Year
1975
Tongue
English
Weight
268 KB
Volume
97
Category
Article
ISSN
0002-7863

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๐Ÿ“œ SIMILAR VOLUMES


Decarboxylative acylation of thiolmalona
โœ Yoshiaki Kobuke; Jun-ichi Yoshida ๐Ÿ“‚ Article ๐Ÿ“… 1978 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 214 KB

In the biosynthesis of fatty acids and polyketides, 1 the malonyl group attached to one of the two sulfhydryl groups (so called "central" SH-group) in the multienzyme complex is decarboxylatively acylated by the acetyl residue attached to the other ("peripheral" SH-group), giving rise to acetothiol