The aqueous cleavage of N-(2-bromoethyl)phthalimide (NBEPH), N-(3-bromopropyl)phth&mide (NBPPH), and N-carbethoxyphthalimide (NCPH) have been studied within the [OH] range of 5 x 10 M to 2 x 10.' M, pH range of 8.82 to 10.62 and 8.06 to 8.66, respective1y:The observed pseudo-first-order rate consta
The resistance to hydrolysis of N,N-dimethyl-N-phenylammoniomethanesulfonate and the improbability of a recently-proposed mechanism of hydrolysis of anilinomethanesulfonates
✍ Scribed by J.F. King; S. Skonieczny
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- French
- Weight
- 142 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
The hydrolysis Of PhN+Me,CH,SO,~ (2) is so slow that a proposed mechanism of hydrolysis of PhNHCH,SO,-Na+ involving sN2 attack of H,O on PhNFl,"Cii,SO,~ may be discounted.
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