The relaxation of O2(1Δg) in condensed systems
✍ Scribed by Michael A.J. Rodgers
- Publisher
- Elsevier Science
- Year
- 1984
- Weight
- 199 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0047-2670
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The same chemiluminescent spectrum of HNO was obtained in both the reaction systems of 0(3P) + CaHe + NO + 02 (\* A,)/02 and H + NO + 02( 'Ag)/Oa. The reaction mechanism for producing the excited HNO is proposed to be -HNO('A') + 02 ( 'Ag) + HNO(3A", + 0s (3X,) , HNOc3A") + 02 ('A,) --t HNO('A") +
The rake constam [or NO+(u) vibrational relaxation by memsrable 02('A ) molecul& is round LO be (3+2)x10-" err? 5-l al room lemperanxc. in comras~ IO the lack of vibrational quenching of NO'(u) by ground-stale 02('X) molecules. [or which the quenching mLe constant <lo-" cm3 s-l. This suggests that N
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