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The relationship between bimolecular rate coefficients for irreversible and reversible diffusion influenced reactions

✍ Scribed by A. Molski

Publisher: Elsevier Science
Year: 1992
Tongue: English
Weight: 471 KB
Volume: 191
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(92)85368-k

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✦ Synopsis

A formulation of the theory for diffusion influenced reversible reaction A+BX in solution is used to study the effect of the back reaction on the bimolecular forward rate coefficient. The formula recently derived by Szabo that relates the forward rate coefficient in the presence of the back reaction to that in its absence is shown to be valid not only when the reaction occurs at the distance of closest approach but also when it can occur over a range of intetparticle distances.

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