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The relationship between 19F chemical shifts and calculated electron densities in perfluorinated annulenes

✍ Scribed by William P. Dailey

Publisher
Elsevier Science
Year
1986
Tongue
French
Weight
200 KB
Volume
27
Category
Article
ISSN
0040-4039

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✦ Synopsis

Ab initio calculations for a series of perfluorinated annulenes suggest that there is a linear correlation between the total charge density at fluorine and the fluorine chemical shift. The STO-30 basis set overestimates the degree of pi-electron donation by fluorine.

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