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The reactivity of the [Re≡O]3+ core toward aromatic 1,2-diamines: the formation of rhenium(V)-imido complexes

✍ Scribed by Giuliano Bandoli; Thomas I.A. Gerber; Joanne Perils; Jan G.H. du Preez


Book ID
108331644
Publisher
Elsevier Science
Year
1998
Tongue
English
Weight
701 KB
Volume
278
Category
Article
ISSN
0020-1693

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The reaction of [TBA][ReOBr 4 (OPPh 3 )] with [HOC 6 H 4 C(H) NC 6 H 4 SH)] and [HOC 6 H 4 -2-P(C 6 H 5 ) 2 ] in methanol yielded [ReO{h 3 -(OC 6 H 4 C(H) NC 6 H 4 S)}{h 2 -OC 6 H 4 P(C 6 H 5 ) 2 }] (1). The coordination environment around rhenium is distorted octahedral with the ONS donors of the S