Concerning the preparation, infrared spectrum and crystal structure of the diethyldithiocarbamate complex of rhenium(V), Re2O3(S2CNEt2)4
β Scribed by D.G. Tisley; R.A. Walton; D.L. Wills
- Publisher
- Elsevier Science
- Year
- 1971
- Weight
- 133 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0020-1650
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The \(\mathrm{CaO}-\mathrm{ZrO}_{2}-\mathrm{SiO}_{2}\) phase diagrami has been the subject of several investigations; two publications have pointed oul the existence of \(\mathrm{Ca}_{2} \mathrm{ZrSi}_{4} \mathrm{O}_{12}\) whereas two other publications deny its existence. This compound has been obt
Novel tetrameric rhenium(V) complexes have been prepared from [ReNCl 2 (PPh 3 ) 2 ] and [ReN(PMe 2 Ph) (S 2 CNEt) 2 ], respectively. [ReNCl 2 (PPh 3 ) 2 ] reacts with 1.5 equivalents of KS 2 CNEt 2 in methanol to yield the unusual dark red species [{cyclo-ReN} 4 (S 2 CNEt 2 . The crystal structure