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Synthesis and characterization of a ‘3+2’ {Re(V)O}3+ core complex carrying the ONS/PO donor atom set

✍ Scribed by Frank J Femia; Xiaoyuan Chen; John W Babich; Jon Zubieta

Book ID
104138504
Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
85 KB
Volume
316
Category
Article
ISSN
0020-1693

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✦ Synopsis

The reaction of [TBA][ReOBr 4 (OPPh 3 )] with [HOC 6 H 4 C(H) NC 6 H 4 SH)] and [HOC 6 H 4 -2-P(C 6 H 5 ) 2 ] in methanol yielded [ReO{h 3 -(OC 6 H 4 C(H) NC 6 H 4 S)}{h 2 -OC 6 H 4 P(C 6 H 5 ) 2 }] (1). The coordination environment around rhenium is distorted octahedral with the ONS donors of the Schiff base and the phosphorus of the phosphinophenolate ligand occupying the equatorial plane, while the axial sites are occupied by the oxo group and the oxygen atom of the PO ligand, as shown by single-crystal X-ray analysis of 1.

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✍ Finn, Robert C.; Lam, Robert; Greedan, John E.; Zubieta, Jon 📂 Article 📅 2001 🏛 American Chemical Society 🌐 English ⚖ 245 KB