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Novel Six-Coordinate Oxorhenium “3 + 2” Mixed-Ligand Complexes Carrying the SNS/PO Donor Atom Set: Synthesis and Characterization

✍ Scribed by Nock, Berthold; Maina, Theodosia; Tisato, Francesco; Papadopoulos, Minas; Raptopoulou, Catherine P.; Terzis, Aris; Chiotellis, Efstratios


Book ID
126107084
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
81 KB
Volume
38
Category
Article
ISSN
0020-1669

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Synthesis and characterization of a ‘3+2
✍ Frank J Femia; Xiaoyuan Chen; John W Babich; Jon Zubieta 📂 Article 📅 2001 🏛 Elsevier Science 🌐 English ⚖ 85 KB

The reaction of [TBA][ReOBr 4 (OPPh 3 )] with [HOC 6 H 4 C(H) NC 6 H 4 SH)] and [HOC 6 H 4 -2-P(C 6 H 5 ) 2 ] in methanol yielded [ReO{h 3 -(OC 6 H 4 C(H) NC 6 H 4 S)}{h 2 -OC 6 H 4 P(C 6 H 5 ) 2 }] (1). The coordination environment around rhenium is distorted octahedral with the ONS donors of the S