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The reactivities of Mo cluster — A selective substitution reaction of the bridging (dtp) ligand and the crystal structure of {Mo3S4(μ-O2CR)(dtp)3(Py)}

✍ Scribed by Lu Shao-Fang; Huang Jian-Quan; Huang Ming-Dong; Huang Jin-Lin

Book ID
112058790
Publisher
John Wiley and Sons
Year
1989
Tongue
English
Weight
535 KB
Volume
7
Category
Article
ISSN
0256-7660

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📜 SIMILAR VOLUMES

Synthesis and Structural Characterizatio
Synthesis and Structural Characterization of the Novel Cluster Compound {[Mo3S7(dtp)3]4⋅I}{(HgI3)3}⋅4 H2O (dtp=S2P(OC2H5)2−)
✍ Jin Chen; Shao-Fang Lu; Zi-Xiang Huang; Rong-Min Yu; Qiang-Jin Wu 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 157 KB 👁 2 views

Reaction of [Mo 3 Y(m-S) 3 (dtp) 4 (H 2 O)] (Y O, S; dtp S 2 P(OC 2 H 5 ) 2 À ) with HgI 2 gave the novel compound {[Mo 3 S 7 (dtp) 3 ] 4 ´I}{(HgI 3 ) 3 } ´4 H 2 O (1), which contains a {[Mo 3 S 7 (dtp) 3 ] 4 ´I} tetramer and (HgI 3 ) À . Compound 1 has been characterized by IR, Raman, UV/Vis, and N