The reactions of tungsten hexafluoride with ethers, thioethers and selenoethers
β Scribed by A.M. Noble; J.M. Winfield
- Publisher
- Elsevier Science
- Year
- 1968
- Weight
- 136 KB
- Volume
- 4
- Category
- Article
- ISSN
- 0020-1650
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π SIMILAR VOLUMES
Anionic and cationic silicon clusters react exothermically with WF6 to give a variety of tungsten and silicon fluorides. All the silicon anionic clusters transfer their charge to WF6. The electron affinities of S&, are estimated to be less than the electron affinity of WF6 (350 kJ/mole (3.6 eV)).
Kinetic and equilibrium results are reported for the reactions of sulphite with the ethyl and phenyl ethers of 2,4,6-trinitrophenol and 2,4,6-trinitrothiophenol in 80/20 (v/v) water/DMSO. In each case 1:1 and 1:2 adducts are observed by reaction of sulphite at one or two unsubstituted ring positions