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Reaction of anionic and cationic silicon clusters with tungsten hexafluoride studied by fourier transform ion cyclotron resonance mass spectrometry

✍ Scribed by W.D. Reents Jr.; M.L. Mandich; V.E. Bondybey

Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
654 KB
Volume
131
Category
Article
ISSN
0009-2614

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✦ Synopsis

Anionic and cationic silicon clusters react exothermically with WF6 to give a variety of tungsten and silicon fluorides. All the silicon anionic clusters transfer their charge to WF6. The electron affinities of S&, are estimated to be less than the electron affinity of WF6 (350 kJ/mole (3.6 eV)).

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