Rate constants for the reactions of OH radicals and Cl atoms with CH,CH,NO>, CH,CH,CH,NO,, CH3CH2CH2CHzN02, and CH,CH2CH2CH,CH2N02 have been determined at 295+3 K and a total pressure of approximately 1 atm. The OH rate data were obtained using both the absolute rate technique of pulse radiolysis co
The reactions of some common electrophiles, CH3 +, NO+, NO2 +, and O2NCH2 +, with monosubstituted benzenes in the gas phase
โ Scribed by Morrison, James D.; Stanney, Keith; Tedder, John M.
- Book ID
- 119995270
- Publisher
- Royal Society of Chemistry
- Year
- 1981
- Tongue
- English
- Weight
- 408 KB
- Volume
- 6
- Category
- Article
- ISSN
- 1472-779X
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๐ SIMILAR VOLUMES
Alkyl and alkylperoxy radicals originating from dimethyl ether have been studied in the gas phase at 296 K. A pulse radiolysis-UV absorption technique was used. Absorption cross-sections were quantified over the wavelength range 220-350 nm. At 230 nm, O'cH3oclJ2 = (4.2 + 0.5)ร 10 -18 cm 2 molecule-l
Pulse radiolysis was used to study the kinetics of the reactions of CH 3 C(O)CH 2 O 2 radicals with NO and NO 2 at By monitoring the rate of formation and decay of NO 2 295 K. using its absorption at the rate constants 400 and 450 nm k(CH C(O)CH O ฯฉ NO) ฯญ (8 ฯฎ 3 2 2 and were de-ฯช12 ฯช12 3 ฯช1 ฯช1 2) ฯซ
The rate constant for the reaction CH302 + NO2 -(products) has been measured directly by flash photolysis and kinetic spectroscopy. At room temperature and a t total pressures between 53 and 580 Torr, k:, = (9.2 f 0.4) X lo8 liter/mole sec so that the rate of formation of the probable primary produc