The Reactions of Methyl Radicals in the Solid-, Liquid-, and Gas-Phase Photolysis of Dimethylmercury
โ Scribed by Rebbert, R. E.; Ausloos, P.
- Book ID
- 126300198
- Publisher
- American Chemical Society
- Year
- 1963
- Tongue
- English
- Weight
- 548 KB
- Volume
- 85
- Category
- Article
- ISSN
- 0002-7863
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๐ SIMILAR VOLUMES
The flash photolysis of biacetyl produces CO, CZH6, and CH3COCH3 as main products, and in small amounts COz, CzH4, and CH3CHO. The rate constants of reactions ( 2) and of' thermally equilibrated radicals were calculated from the amounts of products: ) lo'\* dm3/mol. s k 3 = (2.43 f 0.14) 1O1O dm3/
The rate constant for the reaction of atomic oxygen (0( 3P)) with dimethylmercury has been measured at room temperature at a pressure of about 1 Tot-r using a fast flow system with electron paramagnetic resonance and mass spectrometric detection. Some reaction products were identified. The rate cons
The reaction products of photolysis of acetic anhydride in gas phase at 25"C, where He or C 0 2 was present as buffer gas, were analyzed by gas chromatography. The extent of photodissociation was 52% 2 5% and the extent of intramolecular hydrogen transfer reaction producing acetic acid and ketene wa
Flash photolysis of dimethyl oxalate produced the radicals CH3, CH30, and COOCH3. Thermally equilibrated methoxycarbonyl radicals did not decompose during radicalradical reactions in the presence of 40-tom cyclohexane in the temperature range 298-448 K. Cyclohexyl radicals were also generated during