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The reactions of carbon monoxide at coordinatively unsaturated sites on a platinum surface

โœ Scribed by Y. Iwasawa; R. Mason; M. Textor; G.A. Somorjai

Publisher
Elsevier Science
Year
1976
Tongue
English
Weight
251 KB
Volume
44
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

Photoelectron

spectroscopy has descnbcd the dissociatwc sorption ot carbon monoxide at the steps and kmks of a platmum vicinal surfacc, the sorptwn being aaociatwe a: tcrracc sit%

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The reaction of CO and NH, was performed over M/X (M=Rh, Ru, Pd; X=A1201, SiOz, TiO\*) films. lnfrared spectroscopy was used to monitor the formation of surface intermediates. Isocyanate (NCO) was detected for all of the metals when the support was A1203 or SiO\*, but not for TiOz. The NC0 resided o