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The reaction SO+O2 →SO2 +O

✍ Scribed by D.J. Williams

Publisher: Elsevier Science
Year: 1968
Tongue: English
Weight: 642 KB
Volume: 12
Category: Article
ISSN: 0010-2180
DOI: 10.1016/0010-2180(68)90098-9

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The decay of SO generated in the reaction 0 r0CS-r CO+ SO in the absence of O1 has been studied at 298 K from 2 to 8 Torr, using a tubular Row reactor coupled to a mass spectrometer. The products of the decay of SO are S. SO:. S20. and (SO),. The kinetics of tile decay of SO could be accounted for o

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Flow reactor experiments were performed to study moist CO oxidation in the presence of trace quantities of NO (0-400 ppm) and SO 2 (0-1300 ppm) at pressures and temperatures ranging from 0.5-10.0 atm and 950-1040 K, respectively. Reaction profile measurements of CO, CO 2 , O 2 , NO, NO 2 , SO 2 , an

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Rate coefficients of the title reaction R 31 (SO 2 + O + M → SO 3 + M) and R 56 (SO 2 + HO 2 → SO 3 + OH), important in the conversion of S(IV) to S(VI), were obtained at T = 970-1150 K and ρ ave = 16.2 μmol cm -3 behind reflected shock waves by a perturbation method. Shockheated H 2 /O 2 /Ar mixtur

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The reacttonsof CH30z nitIt SO2 and NO haw been studied bv steady state photo&s of azomethane in the presence of Ot-SOz-SO mixtures at 196 M and I ;Ltm total pressure. Thr quantum yield of NO otidntion by CHxO= m.dicxG is increased substanthlIy when SO? is added ro the system indicating an SOa induc

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Methylperoxy radicals were generated by the flash photolysis of azomethane-oxygen mixtures. The observed broadband spectrum of the CH302 radical is similar, but not identical to those reported previously. The CH:302 decay followed second-order kinetics a t high CH:jOz concentrations with k4, = (2.5