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The reaction of α,β-acetylenic ketones with dicyclohexylborane: Stereoselective synthesis of functionalized trisubstituted olefins

✍ Scribed by George W. Kabalka; Su Yu; Nan-Sheng Li; Ute Lipprandt

Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
187 KB
Volume
40
Category
Article
ISSN
0040-4039

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✦ Synopsis

Allenoxyborinates, easily generated via the 1,4-addition of dicyclohexylborane to a,~acetylenic ketones, react in situ with excess starting ketone to afford stereodefined, functionalized trisubstituted olefins in high yields.

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