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A novel fragmentation reaction of α,β-epoxyketones the synthesis of acetylenic ketones

✍ Scribed by Masato Tanabe; David F. Crowe; Robert L. Dehn


Publisher
Elsevier Science
Year
1967
Tongue
French
Weight
167 KB
Volume
8
Category
Article
ISSN
0040-4039

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✦ Synopsis


We wish to report that p-toluenesulfonylhydrazones of certain o,g%poxyketones undergo a novel fragmentation reaction to yield an acetylene and a ketone as shown in Scheme 1.


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