ChemInform Abstract: Stereoselective Synthesis of Highly Functionalized Trisubstituted Olefins via the Aldol Reaction of Allenoxyborinates with Carbonyl Compounds.
β Scribed by S. Yu; Nan-Sheng Li; George W. Kabalka
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 34 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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π SIMILAR VOLUMES
The Reaction of Ξ±,Ξ²-Acetylenic Ketones with Dicyclohexylborane: Stereoselective Synthesis of Functionalized Trisubstituted Olefins. -Ξ±,Ξ²-Acetylenic ketones (I) (6 compounds) undergo 1,4-addition of dicyclohexylborane to give allenoxyborinate intermediates which react with excess starting ketone to
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