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The reaction of trichloromethyl radicals with hydrogen chlorid and a new estimation of the rate of combination of trichloromethyl radicals

✍ Scribed by I. A. Matheson; H. W. Sidebottom; J. M. Tedder

Book ID
118284902
Publisher
John Wiley and Sons
Year
1974
Tongue
English
Weight
547 KB
Volume
6
Category
Article
ISSN
0538-8066

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πŸ“œ SIMILAR VOLUMES

Some hydrogen abstraction reactions of t
Some hydrogen abstraction reactions of the trichloromethyl radical
✍ Fred B. Wampler; Robert R. Kuntz πŸ“‚ Article πŸ“… 1971 πŸ› John Wiley and Sons 🌐 English βš– 282 KB

The gas phase photolysis of CCl, in the presence of several alkanes has been used to obtain Arrhenius parameters for the abstraction of hydrogen atoms by the cc& radical: (4) Cc1, + RH -% CRCI, + R The following log k4 values were obtained: 2,3-Dimethylbutane C -C ~H I ~ Methy lcy clohexane log k4 1

Rate constants for the combination of tr
Rate constants for the combination of trichloromethyl radicals and the electron-transfer reaction between hydroxymethyl radicals and carbon tetrachloride in solution
✍ H. Paul πŸ“‚ Article πŸ“… 1979 πŸ› John Wiley and Sons 🌐 English βš– 728 KB

## Abstract The rate constant for the bimolecular combination of trichloromethyl radicals in methanol is determined as a function of temperature by steady‐state kinetics and electron‐spin resonance with modulated radical initiation. The rate constant is in accord with the Smoluchowski equation and