The equilibrium constant for the first thiocyanate addition to Co(W)tetra(3-N-methylpyridyl)porphine is a factor of two smaller than for the less basic 4-N-methylporphine isomer. This effect is primarily due to a larger Co-SCN dissociation rate constant for the 3-isomer.
The reaction of thiocyanate and thiourea with rhodium(III) aqua ions
✍ Scribed by Carlos Dücker-Benfer; Michael Schmülling; Rudi Eldik; Donald A. House
- Publisher
- Springer
- Year
- 1993
- Tongue
- English
- Weight
- 116 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0340-4285
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