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Kinetic study of anation reaction of meso-tetrakis-(p-sulfonatophenyl)porphinatodiaquaruthenate(III) with thiocyanate ion in aqueous solution

โœ Scribed by Kenneth R Ashley; Hai Huang


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
373 KB
Volume
248
Category
Article
ISSN
0020-1693

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High-valent oxo-iron(IV) species are commonly proposed as the key intermediates in the catalytic mechanisms of iron enzymes. Water-soluble iron(III) tetrakis-5,10,15,20-(N-methyl-4-pyridyl)porphyrin (Fe(III)TMPyP) has been used as a model of heme-enzyme to catalyse the hydrogen peroxide (H 2 O 2 ) o