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The aquation reaction of methanol- and ethanoI-pentaamminecobalt(III) and rhodium(III) cations

✍ Scribed by E. Borghi; F. Monacelli

Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
414 KB
Volume
23
Category
Article
ISSN
0020-1693

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✦ Synopsis

The aquation reaction of M(NHJSOHR3' cations (M = Co, Rh and R = CH3, C2H5) has been investigated by kinetic techniques. The kinetic parameters for the substitution of the coordinated alcohol molecule by water, when compared with those for the waterexchange reaction (R = H), confirm the previous suggestion that an associative interchange mechanism is operating in the substitution reactions of pentaamminerhodium(IH) compounds.

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