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The reaction of potassium germyl with boron trimethyl

✍ Scribed by Esther R. De Staricco; Chris Riddle; William L. Jolly

Book ID
118910035
Publisher
Elsevier Science
Year
1973
Weight
170 KB
Volume
35
Category
Article
ISSN
0022-1902

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Hydrogen abstraction from boron trimethyl has been studied using the abstracting radicals CF3 and CD3, from the photolysis of the corresponding ketones over the temperature range of 150Β° to 300Β°C. The following Arrhenius parameters were obtained: 98 kcal/mole (CFJ + BMe3); log A = 11.6, E = 6.59 kc