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Study of pyridine and quinoline polymerization involving reactions with trimethyl boron

โœ Scribed by R.F. Smirnov; B.I. Tikhomirov; M.I. Bitsenko; A.I. Yakubchik


Book ID
118359603
Publisher
Elsevier Science
Year
1971
Weight
541 KB
Volume
13
Category
Article
ISSN
0032-3950

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๐Ÿ“œ SIMILAR VOLUMES


The reactions of CF3 and CD3 radicals wi
โœ T. N. Bell; A. E. Platt ๐Ÿ“‚ Article ๐Ÿ“… 1971 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 453 KB

Hydrogen abstraction from boron trimethyl has been studied using the abstracting radicals CF3 and CD3, from the photolysis of the corresponding ketones over the temperature range of 150ยฐ to 300ยฐC. The following Arrhenius parameters were obtained: 98 kcal/mole (CFJ + BMe3); log A = 11.6, E = 6.59 kc