The reaction of ozone with MPAN, CH2=C(CH3)C(O)OONO2
β Scribed by Grosjean, Daniel; Grosjean, Eric; Williams, Edwin L.
- Book ID
- 126249725
- Publisher
- American Chemical Society
- Year
- 1993
- Tongue
- English
- Weight
- 606 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0013-936X
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π SIMILAR VOLUMES
The gas phase reaction of the hydroxyl radical with the unsaturated peroxyacyl nitrate has been studied at 298 2 2 K and atmospheric pressure. The OH-MPAN reaction rate constant relative to that of OH + n-butyl nitrate is 2.08 2 0.25. This ratio, together with a literature rate constant of 1.74 X c
Based on a n FTIR-product study of the photolysis of mixtures containing Br,-CH3CH0 and Br,-CH3CHO-HCHO in 700 torr of N,, the rate constant for the reaction Br + CHBCHO + HBr + CH3C0 was determined to be 3.7 x lo-', cm3 molecule-' sf'. In addition, the selective photochemical generation of Br at A
## Abstract Pulse radiolysis techniques were used to measure the gas phase UV absorption spectra of the title peroxy radicals over the range 215β340 nm. By scaling to Ο(CH~3~O~2~)~240 nm~ = (4.24 Β± 0.27) Γ 10^β18^, the following absorption cross sections were determined: Ο(HO~2~)~240 nm~ = 1.29 Β± 0