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Rate coefficient for the reaction of OH with CH2C(CH3)C(O)OONO2 (MPAN)

✍ Scribed by John J. Orlando; Geoffrey S. Tyndall; Steven B. Bertman; Wangchun Chen; James B. Burkholder


Book ID
114377893
Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
117 KB
Volume
36
Category
Article
ISSN
1352-2310

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Gas phase reaction of the hydroxyl radic
✍ Daniel Grosjean; Edwin L. Williams II; Eric Grosjean 📂 Article 📅 1993 🏛 John Wiley and Sons 🌐 English ⚖ 567 KB

The gas phase reaction of the hydroxyl radical with the unsaturated peroxyacyl nitrate has been studied at 298 2 2 K and atmospheric pressure. The OH-MPAN reaction rate constant relative to that of OH + n-butyl nitrate is 2.08 2 0.25. This ratio, together with a literature rate constant of 1.74 X c