The rate coefficient for the reaction of the peroxypropionyl radical (C 2 H 5 C(O)O 2 ) with NO was measured with a laminar flow reactor over the temperature range 226-406 K. The C 2 H 5 C(O)O 2 reactant was monitored with chemical ionization mass spectrometry. The measured rate coefficients are k(T
โฆ LIBER โฆ
Direct Measurement of the Rate Coefficient for the CH 2 C(CH 3 )C(O)O 2 + NO Reaction Using Chemical Ionization Mass Spectrometry
โ Scribed by de Gouw, Joost A.; Howard, Carleton J.
- Book ID
- 126789532
- Publisher
- American Chemical Society
- Year
- 1997
- Tongue
- English
- Weight
- 132 KB
- Volume
- 101
- Category
- Article
- ISSN
- 1089-5639
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Pulse radiolysis was used to study the kinetics of the reactions of CH 3 C(O)CH 2 O 2 radicals with NO and NO 2 at By monitoring the rate of formation and decay of NO 2 295 K. using its absorption at the rate constants 400 and 450 nm k(CH C(O)CH O ฯฉ NO) ฯญ (8 ฯฎ 3 2 2 and were de-ฯช12 ฯช12 3 ฯช1 ฯช1 2) ฯซ