The reaction of organolithium reagents with perfluorovinyl derivatives of tin and silicon.

✍ Scribed by Dietmar Seyferth; Tadashi Wada; Gunter Raab

• Book ID: 104249862
• Publisher: Elsevier Science
• Year: 1960
• Tongue: French
• Weight: 171 KB
• Volume: 1
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(01)99372-4

✦ Synopsis

We have investigated the action of organollthiurn reagmts onper-fluoro~ztnyl derivatives of silicon an& tin and have obtained very eQn%&r results, tiz.,an addition reaction with perfluorovinyl,s%l.anes and an exchange reaction with ~~1~~~~~1~~ coqounds which gives the new per-~~~v~nyl~~th~~l reagerlt, c&=m. The reaction between triethylpex%LumovinylsKlane~ and organolithium -' On leave from the shin-Etsu tt&nk%csl Whtstry Oo., Ltd., !I!oky0, J&an. 3 D. Sey%wth and &%.A. Weiner, t2hem. an8 IA {Im&on~ kO2 (1959). ' D. Seyferth, K.A. 5rkd3.e snd G. Raab, Angew. Chem. '& n(lp60).

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