The rate constant for the reaction of O(") with H202 was measured as a function of temperature and the [H202]0/[0]0 ratio. The numerical solution of the appropriate rate equations was used to arrive a t a mechanism which adequately describes our results and the rather divergent data in the literatur
The reaction of O(1D) with H2O and the reaction of OH with C3H6
β Scribed by R. Simonaitis; Julian Heicklen
- Publisher
- John Wiley and Sons
- Year
- 1973
- Tongue
- English
- Weight
- 512 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0538-8066
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π SIMILAR VOLUMES
The reaction of CF3 radicals with Ha0 (D20) has been studied over the range of 533-723 K using the photolysis and the pyrolysis of CFJ as the free radical source. Arrhenius pa- rameters for the reactions where X = H or D, relative to CF:j radical recombination are given by log kHlkf'2 = (5.12 f 0.1
The rate of reaction of O(lD2) with X20 relative to that of reaction with neopentane has been determined by a competitive method. The value obtained, kI.&&op\_ = 0.38, is in good agreement with that determined previously\_ in this laboratory. by a different experimental technique. It is aiso fomd th
We report the observation of the O-+H,O+OH-+OH ion-molecule reaction following photodissociation of 0, within the 0: .H20 ion-dipole complex. Photoexcitation of the 0~ A % ,+X 'lIn dissociative transition in the 200-300 nm region initiates the reaction. The 0-'H20 reaction intermediate is the domina