Relative rate of reaction of O(1D2) with H2O
✍ Scribed by G. Paraskevopoulos; R.J. Cvetanović
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- English
- Weight
- 310 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
✦ Synopsis
The rate of reaction of O(lD2) with X20 relative to that of reaction with neopentane has been determined by a competitive method. The value obtained, kI.&&op_ = 0.38, is in good agreement with that determined previously_ in this laboratory. by a different experimental technique. It is aiso fomd that Lo does not deactivate O[lD9) to 0t3P).
📜 SIMILAR VOLUMES
O ( l D ) , produced from the photolysis ofN,O at 2139 A, reacts with N,O in accord with: We have used the method of chemical difference to obtain an accurate measure of k,/k, = 0.59 f 0.01. Furthermore, the quantum yield of production of O ( , P ) , either on direct photolysis or on deactivation o
Rate coefficients, in units of 10-~0 cm 3 molecule-~ s-~, for the O(~D) reactions with H2, D 2 and HD at 298 K were determined to be 1.2 \_\_\_ 0.1, 1.1 + 0.1, and 1.2 + 0.1, respectively. The H atom yield in the O(~ D) + HD reaction, relative to that in the O(ID) + H 2 reaction, was measured to be