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Relative rate of reaction of O(1D2) with H2O

✍ Scribed by G. Paraskevopoulos; R.J. Cvetanović


Publisher
Elsevier Science
Year
1971
Tongue
English
Weight
310 KB
Volume
9
Category
Article
ISSN
0009-2614

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✦ Synopsis


The rate of reaction of O(lD2) with X20 relative to that of reaction with neopentane has been determined by a competitive method. The value obtained, kI.&&op_ = 0.38, is in good agreement with that determined previously_ in this laboratory. by a different experimental technique. It is aiso fomd that Lo does not deactivate O[lD9) to 0t3P).


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Rate coefficients, in units of 10-~0 cm 3 molecule-~ s-~, for the O(~D) reactions with H2, D 2 and HD at 298 K were determined to be 1.2 \_\_\_ 0.1, 1.1 + 0.1, and 1.2 + 0.1, respectively. The H atom yield in the O(~ D) + HD reaction, relative to that in the O(ID) + H 2 reaction, was measured to be