The Reaction of Methyl Radicals with Nitric Oxide
โ Scribed by Maschke, A.; Shapiro, B. S.; Lampe, F. W.
- Book ID
- 126087734
- Publisher
- American Chemical Society
- Year
- 1964
- Tongue
- English
- Weight
- 703 KB
- Volume
- 86
- Category
- Article
- ISSN
- 0002-7863
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๐ SIMILAR VOLUMES
The reaction CHs+NO (+M) +CH,NO (+M) was initiated by pulse radiolysis of acetone/nitric oxide mixtures and the kinetics of methyl radicals was studied by time-resolved infrared absorption spectroscopy. The rate constant was found to be strongly pressure dependent in the range of p( M ) =6.5-150 mba
By allowing dimethyl peroxide ( 10-4M) to decompose in the presence of nitric oxide (4.5 X lOW5M), nitrogen dioxide (6.5 X 10-5M) and carbon tetrafluoride (500 Torr), it has been shown that the ratio kzlkz, = 2.03 f 0.47: CH30 + NO -CH30NO (reaction 2) and CH30 + NO2 -CH30N02 (reaction 2'). Deviatio