๐”– Bobbio Scriptorium
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The Reaction of Methyl Radicals with Nitric Oxide

โœ Scribed by Maschke, A.; Shapiro, B. S.; Lampe, F. W.


Book ID
126087734
Publisher
American Chemical Society
Year
1964
Tongue
English
Weight
703 KB
Volume
86
Category
Article
ISSN
0002-7863

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The reaction CHs+NO (+M) +CH,NO (+M) was initiated by pulse radiolysis of acetone/nitric oxide mixtures and the kinetics of methyl radicals was studied by time-resolved infrared absorption spectroscopy. The rate constant was found to be strongly pressure dependent in the range of p( M ) =6.5-150 mba

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By allowing dimethyl peroxide ( 10-4M) to decompose in the presence of nitric oxide (4.5 X lOW5M), nitrogen dioxide (6.5 X 10-5M) and carbon tetrafluoride (500 Torr), it has been shown that the ratio kzlkz, = 2.03 f 0.47: CH30 + NO -CH30NO (reaction 2) and CH30 + NO2 -CH30N02 (reaction 2'). Deviatio