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Overall Rate Constant Measurements of the Reaction of Hydroxy- and Chloroalkylperoxy Radicals Derived from Methacrolein and Methyl Vinyl Ketone with Nitric Oxide

✍ Scribed by Hsin, Hong Yuan; Elrod, Matthew J.


Book ID
127370055
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
182 KB
Volume
111
Category
Article
ISSN
1089-5639

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Product formation from the reaction of t
✍ Eric S. C. Kwok; Sara M. Aschmann; Janet Arey; Roger Atkinson πŸ“‚ Article πŸ“… 1996 πŸ› John Wiley and Sons 🌐 English βš– 707 KB

Using a relative rate method, rate constants for the gas-phase reactions OF the NO, radical with methacrolein and methyl vinyl ketone were determined to be ( 4 4 2 1.7) X cm' molecule-' s-' and < 6 X cm3 molecule-' S S ' , respectively, at 296 ? 2 K. The molar formation yields of rnethacrolein and m