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Stable carbon kinetic isotope effects for the production of methacrolein and methyl vinyl ketone from the gas-phase reactions of isoprene with ozone and hydroxyl radicals

โœ Scribed by Richard Iannone; Ralf Koppmann; Jochen Rudolph

Book ID
113480315
Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
409 KB
Volume
44
Category
Article
ISSN
1352-2310

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Product formation from the reaction of the NO3 radical with isoprene and rate constants for the reactions of methacrolein and methyl vinyl ketone with the NO3 radical
โœ Eric S. C. Kwok; Sara M. Aschmann; Janet Arey; Roger Atkinson ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 707 KB

Using a relative rate method, rate constants for the gas-phase reactions OF the NO, radical with methacrolein and methyl vinyl ketone were determined to be ( 4 4 2 1.7) X cm' molecule-' s-' and < 6 X cm3 molecule-' S S ' , respectively, at 296 ? 2 K. The molar formation yields of rnethacrolein and m