The Reaction of Nitric Oxide with Organic Peroxyl Radicals
β Scribed by S. Padmaja; R.E. Huie
- Book ID
- 115573455
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 273 KB
- Volume
- 195
- Category
- Article
- ISSN
- 0006-291X
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Alrstract--Trialkyl phosphites react with cyanoisopropylperoxyl radicals, generated by thermolysis of azobis(isobutyronitrile) in the presence of oxygen, to give the corresponding phosphates with rate constants of the order of 103 M -~ sec -~ at 65Β°C. Phenyl phosphites are oxidized also. A small amo
By allowing dimethyl peroxide ( 10-4M) to decompose in the presence of nitric oxide (4.5 X lOW5M), nitrogen dioxide (6.5 X 10-5M) and carbon tetrafluoride (500 Torr), it has been shown that the ratio kzlkz, = 2.03 f 0.47: CH30 + NO -CH30NO (reaction 2) and CH30 + NO2 -CH30N02 (reaction 2'). Deviatio
## Abstract To investigate the possibility of the carbyne radical CCN in removal of nitric oxide, a detailed computational study is performed at the Gaussianβ3//B3LYP/6β31G(d) level on the CCN + NO reaction by constructing the singlet and triplet electronic state [C~2~N~2~O] potential energy surfac