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The Reaction of Hydrogen Atoms with Isobutene

โœ Scribed by M. J. Lexton, R. M. Marshall and J. H. Purnell


Book ID
123661463
Publisher
The Royal Society
Year
1971
Tongue
English
Weight
480 KB
Volume
324
Category
Article
ISSN
0962-8444

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Hydrogen atoms, generated by the mercury (3P1) sensitization of Hz, were allowed to react with dimethyldisulfide in the temperature range of 25-155'C. The only retrievable product is methanethiol, formed in the primary metathetical reaction H + CH3SSCH3 k,' CH3SH t CH3S. The intermediacy of thiyl ra