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The Reaction of Hydrogen Atoms with Isobutene

โœ Scribed by Lexton, M. J.; Marshall, R. M.; Purnell, J. H.


Book ID
120151638
Publisher
The Royal Society
Year
1971
Tongue
English
Weight
591 KB
Volume
324
Category
Article
ISSN
0962-8444

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Hydrogen atoms, generated by the mercury (3P1) sensitization of Hz, were allowed to react with dimethyldisulfide in the temperature range of 25-155'C. The only retrievable product is methanethiol, formed in the primary metathetical reaction H + CH3SSCH3 k,' CH3SH t CH3S. The intermediacy of thiyl ra