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The reaction of diphenyldiazomethane with β-Dimethylaminoethanol: (Preliminary communication)

✍ Scribed by T. Bultsma; W. Th. Nauta


Book ID
104587200
Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
143 KB
Volume
85
Category
Article
ISSN
0165-0513

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📜 SIMILAR VOLUMES


On the reaction of diphenyldiazomethane
✍ G.F. Bettinetti; A. Donetti; P. Grűnanger 📂 Article 📅 1966 🏛 Elsevier Science 🌐 French ⚖ 160 KB

## Diphenyldiazomethane (DDM) has been shawn, chiefly through the work of Schunberg and co-workers, l-4 to react with o-quinones. and with activated CO double bonds, yielding benzodioxoles resp. epoxidee.

The Total Synthesis of (±) β-Acorenol. P
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## Abstract Die erste Totalsynthese des Spiro‐sesquiterpenes β‐Acorenol, ausgehend vom bekannten Cyclohex‐1‐enylessigsäureäthylester, wird beschrieben. Die Schlüsselstufe **2** → **3** + **4** verläuft über eine thermische intramolekulare En‐Reaktion.