Excitation of chemiluminescence in the reaction of benzophenone-O-oxide with diphenyldiazomethane. Quantum-induced decomposition of diphenyldiazomethane

A study of the bimolecular intersystem c

A study of the bimolecular intersystem crossing reaction induced in the first excited singlet of SO2 by collisions with O2 and other atmospheric gases

✍ Fred B. Wampler; Jack G. Calvert; Edward K. Damon 📂 Article 📅 1973 🏛 John Wiley and Sons 🌐 English ⚖ 524 KB

The relative intensities of phosphorescence of S02(3B1) molecule: have been determined following the optical excitation of S02('BI) molecules by a 2662 A laser pulse. From a kinetic treatment of these measurements, the intersystem crossing ratio, k2b/(klb + kzb), was determined; SOZ( With ha = 0 2