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The reaction of diaziridine with diphenylketene

✍ Scribed by Mitsuo Komatsu; Yoshiki Ohshiro; Toshio Agawa

Publisher
Elsevier Science
Year
1972
Tongue
French
Weight
125 KB
Volume
13
Category
Article
ISSN
0040-4039

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✦ Synopsis

Compared with the reaction of oxaziridines with diphenylketene forming tetraphenylsuccinimide derivatives accompanied by elimination of carbonyl compounds,' the reaction of 1,2,3-trialkyldiaziridine with the ketene showed quite different

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Cycloaddition Reactions of Ξ±-Lactams wit
Cycloaddition Reactions of Ξ±-Lactams with Diphenylketene
✍ Gerrit L'abbΓ©; Alex Van Asch; Suzanne Toppet πŸ“‚ Article πŸ“… 2010 πŸ› Wiley (John Wiley & Sons) βš– 95 KB πŸ‘ 1 views

In an excellent review' Lengyel and Sheehan have discussed the chemistry of alactams and pointed out that they appear to be unreactive as 1,3-dipoles in cycloaddition reactions. However, a-lactams possess a more than reasonable tendency to undergo ring opening by cleavage of the (sp3)C-N bond' in or