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Cycloaddition Reactions of α-Lactams with Diphenylketene

✍ Scribed by Gerrit L'abbé; Alex Van Asch; Suzanne Toppet

Publisher
Wiley (John Wiley & Sons)
Year
2010
Weight
95 KB
Volume
87
Category
Article
ISSN
0037-9646

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✦ Synopsis

In an excellent review' Lengyel and Sheehan have discussed the chemistry of alactams and pointed out that they appear to be unreactive as 1,3-dipoles in cycloaddition reactions. However, a-lactams possess a more than reasonable tendency to undergo ring opening by cleavage of the (sp3)C-N bond' in order to react as a 1,3-dipolar component in cycloadditions.

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