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The reaction of (butadiene)tantalocene cation with bulky carbonyl derivatives

✍ Scribed by Hans Christian Strauch; Rolf Roesmann; Silke Pacheiner; Gerhard Erker; Roland Fröhlich; Birgit Wibbeling

Book ID
108354792
Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
147 KB
Volume
584
Category
Article
ISSN
0022-328X

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Formation of the [(s-trans-η4-Butadiene)TaCp*Cp]+ Cation and Its Reaction with Organic Carbonyl Derivatives
✍ Hans Christian Strauch; Gerhard Erker; Roland Fröhlich; Maija Nissinen 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 331 KB

Group-5 bent metallocene cation complexes / (Butadiene)tantalocene cation / (s-trans-η 4 -Butadiene)metal complex / Ethene polymerization / Metallocenes / Homogeneous catalysis (Butadiene)TaCp\*Cl 2 (6) was treated with CpNa to yield (η 2 -cation complex 8 reacts with ketones (acetone, adamantanone)