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Synthesis of ( s - trans -η 4 -Butadiene)tantalocene Cation and Its CC-Coupling Reactions with Ketones, Nitriles, and Alkynes †

✍ Scribed by Strauch, Hans Christian; Erker, Gerhard; Fröhlich, Roland

Book ID
126793527
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
290 KB
Volume
17
Category
Article
ISSN
0276-7333

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Formation of the [(s-trans-η4-Butadiene)
Formation of the [(s-trans-η4-Butadiene)TaCp*Cp]+ Cation and Its Reaction with Organic Carbonyl Derivatives
✍ Hans Christian Strauch; Gerhard Erker; Roland Fröhlich; Maija Nissinen 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 331 KB

Group-5 bent metallocene cation complexes / (Butadiene)tantalocene cation / (s-trans-η 4 -Butadiene)metal complex / Ethene polymerization / Metallocenes / Homogeneous catalysis (Butadiene)TaCp\*Cl 2 (6) was treated with CpNa to yield (η 2 -cation complex 8 reacts with ketones (acetone, adamantanone)