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The reaction of benzylsulfonyl halides with phenyllithium: Preparation of sulfones

✍ Scribed by Yasuhiko Shirota; Toshikazu Nagai; Niichiro Tokura


Publisher
Elsevier Science
Year
1967
Tongue
French
Weight
693 KB
Volume
23
Category
Article
ISSN
0040-4020

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A synthesis is described of alkyl chlorides by reaction of methoxy hydroperoxides, prepared from 1-alkenes by oronisation in methanol, with ferric chloride: RCH-CH,\_\*RCH(OOH)OCH,\_\*R= -?RCl. Yields of 1-chlorotetradecane were about 60%; those of other halides from 38 to 57%. INTRGDUCTION When alk