The reaction of benzylsulfonyl halides with phenyllithium: Preparation of sulfones
β Scribed by Yasuhiko Shirota; Toshikazu Nagai; Niichiro Tokura
- Publisher
- Elsevier Science
- Year
- 1967
- Tongue
- French
- Weight
- 693 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0040-4020
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π SIMILAR VOLUMES
Reaeived 4 June 1959) A STKDY of the addition of phenyllithimn to 3-substituted pyridinez m.z undertaken to detemine the orientatfon of the entering phenyl group, . While this work was in progrees W&leg et al\*' reported that the reaction of 3-phenylpyridine I(R -C H 65 ) with phenyllithium II wag a
A synthesis is described of alkyl chlorides by reaction of methoxy hydroperoxides, prepared from 1-alkenes by oronisation in methanol, with ferric chloride: RCH-CH,\_\*RCH(OOH)OCH,\_\*R= -?RCl. Yields of 1-chlorotetradecane were about 60%; those of other halides from 38 to 57%. INTRGDUCTION When alk