✦ LIBER ✦

The Reaction of As4Sn (n = 3, 4) and As2S3 with (C5Me4R)2Co2(CO)2 (R = Me, Et): Fragmentation and Reassembling of Main-Group Ligands by Organometallic Complexes

✍ Scribed by Brunner, Henri ;Kauermann, Heike ;Poll, Ludwig ;Nuber, Bernhard ;Wachter, Joachim

Publisher: Wiley (John Wiley & Sons)
Year: 1996
Tongue: English
Weight: 608 KB
Volume: 129
Category: Article
ISSN: 0009-2940
DOI: 10.1002/cber.19961290611

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Ligand Extrusion from the As4S4-Cage by

Ligand Extrusion from the As4S4-Cage by [C5Me5(CO)2Mo]2: Formation of (C5Me5)2Mo2(CO)4(μ,η2-As2), C5Me5(CO)2Mo(η3-As3), and (C5Me5)2Mo2As2S3

✍ Prof. Dr. Ivan Bernal; Prof. Dr. Henri Brunner; Walter Meier; Heike Pfisterer; D 📂 Article 📅 1984 🏛 John Wiley and Sons 🌐 English ⚖ 236 KB 👁 1 views

Complexes of the (Tetramethylcyclobutadi

Complexes of the (Tetramethylcyclobutadiene)cobalt Fragment with Boratabenzene Ligands and an Unprecedented Formation of a Borabenzene Complex − Structures of (C4Me4)Co(3,5-Me2C5H3BSnMe3) with an Sn−B Bond and of the Dinuclear Complex [(C4Me4)Co(3,5-Me2C5H3B)]2O

✍ Gerhard E. Herberich; Tushar S. Basu Baul; Ulli Englert 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 294 KB 👁 2 views

The yellow-orange boratabenzene complex Cb\*Co(3,5-Me 2 C 5 H 3 BNMe 2 ) (1) (Cb\* = C 4 Me 4 ) was readily obtained from [Cb\*Co(NCMe) 3 ]PF 6 and Li(TMEDA)(3,5-Me 2 C 5 H 3 BNMe 2 ). Methanolysis of 1 afforded Cb\*Co(3,5-Me 2 C 5 H 3 BOMe) (2). Complex 2 reacted with MeLi and with BCl 3 to give th

Organometallic Niobium and Tantalum Comp

Organometallic Niobium and Tantalum Complexes with Primary Phosphine Ligands: Syntheses and Molecular Structures of [Cp*MCl4(PH2R)] (M = Nb, Ta; Cp* = C5Me5;R = But, Ad, Cy, Ph, 2, 4, 6-Me3C6H2 (Mes))

✍ Steffen Blaurock; Evamarie Hey-Hawkins 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 German ⚖ 173 KB 👁 2 views

The reaction of [Cp\*MCl 4 ] (M ϭ Nb, Ta; Cp\* ϭ C 5 Me 5 ) with PH 2 R in toluene at room temperature gives the primary phosphine complexes [Cp\*MCl 4 (PH 2 R)] [Cp\* ϭ C 5 Me 5 ; M ϭ Nb: R ϭ Bu t (1a), Ad (2a), Cy (3a), Ph (4a), 2,4,6-Me 3 C 6 H 2 (Mes) (5a); M ϭ Ta: R ϭ Bu t (1b), Ad (2b), Cy (3b

Reactivity of the Inversely Polarized Ar

Reactivity of the Inversely Polarized Arsaalkenes R–As=C(NMe2)2 {R = [(η5-C5Me5)(CO)2Fe], tBuC(O), 4-Et–C6H4C(O)} towards Phosphavinylidene Complexes [η5-(C5H5)(CO)2M=P=C(SiMe3)2] (M = Mo, W)

✍ Lothar Weber; Philipp Bayer; Stefan Uthmann; Thomas Braun; Hans-Georg Stammler; 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 177 KB

Organometallic Molybdenum(V) Complexes w

Organometallic Molybdenum(V) Complexes with Promary Phosphane Ligands — Syntheses, Spectroscopic Properties, and Crystal Structures of [Cp′MoCl4(PH2R)] (R=2,4,6-Pri3C6H2, Cyclohexyl, Cp′=C5H4Me)

✍ Felsberg, Reinhard ;Blsurock, Steffen ;Jelonek, Svea ;Gelbrich, Thomas ;Kirmse, 📂 Article 📅 1997 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 572 KB

Polymerization of propylene with the [Ar

Polymerization of propylene with the [ArN(CH2)3NAr]TiCl2 (Ar = 2,6-iPr2C6H3) complex using R3Al/Ph3CB(C6F5)4 (R = Me, Et, iBu) as cocatalyst

✍ Jizhu Jin; Shingo Tsubaki; Toshiya Uozumi; Tsuneji Sano; Kazuo Soga 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 367 KB 👁 1 views

Polymerization of propylene was conducted at 0 -150°C with the [ArN(CH2)3NAr]TiClz (Ar = 2,6-'Pr2C6H3) complex using a mixture of ~a l k y l a l u m i n i ~ (AIR3, R = methyl, ethyl and isobutyl) and Ph3CB(C&& as cocatalyst. When AlMe3 or AlEt3 was employed, atactic polypropylene (PP) was selectivel