The reaction of [Cp\*MCl 4 ] (M ϭ Nb, Ta; Cp\* ϭ C 5 Me 5 ) with PH 2 R in toluene at room temperature gives the primary phosphine complexes [Cp\*MCl 4 (PH 2 R)] [Cp\* ϭ C 5 Me 5 ; M ϭ Nb: R ϭ Bu t (1a), Ad (2a), Cy (3a), Ph (4a), 2,4,6-Me 3 C 6 H 2 (Mes) (5a); M ϭ Ta: R ϭ Bu t (1b), Ad (2b), Cy (3b
✦ LIBER ✦
Organometallic Molybdenum(V) Complexes with Promary Phosphane Ligands — Syntheses, Spectroscopic Properties, and Crystal Structures of [Cp′MoCl4(PH2R)] (R=2,4,6-Pri3C6H2, Cyclohexyl, Cp′=C5H4Me)
✍ Scribed by Felsberg, Reinhard ;Blsurock, Steffen ;Jelonek, Svea ;Gelbrich, Thomas ;Kirmse, Reinhard ;Voigt, Andreas ;Hey-Hawkins, Evamarie
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1997
- Tongue
- English
- Weight
- 572 KB
- Volume
- 130
- Category
- Article
- ISSN
- 0009-2940
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