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The reaction of aromatic nitroso compounds with cyanide ion in aprotic solvents

✍ Scribed by John C. Trisler; Philip H. Deland; Marvin M. Goodgame

Publisher
Elsevier Science
Year
1975
Tongue
French
Weight
194 KB
Volume
16
Category
Article
ISSN
0040-4039

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✦ Synopsis

A review of the chemical literature reveals a number of addition reactions to the nitroso functional group which appear analogous in many respects to those observed for carbonyl compounds.

1 It is also recognized that nitroso compounds are excellent acceptors of electrons from anionic species to yield corresponding radical anions. 2

πŸ“œ SIMILAR VOLUMES

Colorimetric determination of dinitrophe
Colorimetric determination of dinitrophenylamine acids with cyanide ion in dipolar aprotic solvents
✍ J.A. Vinson; L.D. Pepper πŸ“‚ Article πŸ“… 1977 πŸ› Elsevier Science 🌐 English βš– 321 KB

Dinitrophenyl (DNP)-amino acids have been calorimetrically determined by making use of the red color formed by their reaction with cyanide in dimethy~suifoxide or dimethyiacetamide. The extinction coefficients are over 20,000, making this method more sensitive than previous methods which have used

Solvent effects in the photoinduced reac
Solvent effects in the photoinduced reactions of nitroaromatics with cyanide ion
✍ R.L. Letsinger; R.R. Hautala πŸ“‚ Article πŸ“… 1969 πŸ› Elsevier Science 🌐 French βš– 245 KB

We have found that substituent groups and solvents may have striking effects on the rates of bimolecular reactions involving nucleophiles and photoexcited nitroaromatic compounds. As representative cases, data on reactions of cyanide ion and 4-nitroanisole, l-nitronaphtbalene. and 4-methoxy-1-nitron