The reaction between tetracyclone and superoxide radical anion
โ Scribed by I. Rosenthal; A. Frimer
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- French
- Weight
- 127 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
We wish to report rate constants for the reaction of superoxide anion radical, 02', with various aliphatic bromides in dimethylsulfoxide (DMSO) solution. The results suggest that 02; is one of the most potent nucleophiles yet studied. Superoxide ion is the radical anion derived by adding an electro
The disproportionation of superoxide radical anions catalyzed by nickel superoxide dismutase was investigated in detail using density functional theory. The structures of each stationary point and the transition states were located so that the reaction pathways were determined. The results indicated
Cyclohex-2-en-l-ones with available acidic hydrogens undergo base catalyzed autoxidation in the presence of KO2/18-crown-6 in benzene yielding 2-hydroxycyclohexa-2,5-dien-lones in the case of 4,4-and 5,5\_disubstituted substrates and 2,3-epoxycyclohexanones in the case of 6,6-disubstituted analogs;