Determination of superoxide (O2−) radical anion reaction rates using pulse radiolysis
✍ Scribed by C.L. Greenstock; G.W. Ruddock
- Publisher
- Elsevier Science
- Year
- 1976
- Weight
- 237 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0020-7055
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Cyclohex-2-en-l-ones with available acidic hydrogens undergo base catalyzed autoxidation in the presence of KO2/18-crown-6 in benzene yielding 2-hydroxycyclohexa-2,5-dien-lones in the case of 4,4-and 5,5\_disubstituted substrates and 2,3-epoxycyclohexanones in the case of 6,6-disubstituted analogs;
The rate constants for reactions (4) and (5) ( 4 ) CFCI,O, 7 NO -+CFCI,O + NO, ( 5 ) CFCI,O, + NO, + M -CFCI,O,NO, -M were determined at room temperature by pulsed laser photolysis and time resolved mass spectrometry. A description of the experimental setup is given. CFCI,O, radicals were generated