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The remarkable nucleophilicity of superoxide anion radical. rate constants for reaction of superoxide ion with aliphatic bromides.

✍ Scribed by Wayne C. Danen; R.Jay Warner

Publisher
Elsevier Science
Year
1977
Tongue
French
Weight
250 KB
Volume
18
Category
Article
ISSN
0040-4039

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✦ Synopsis

We wish to report rate constants for the reaction of superoxide anion radical, 02', with various aliphatic bromides in dimethylsulfoxide (DMSO) solution. The results suggest that 02; is one of the most potent nucleophiles yet studied.

Superoxide ion is the radical anion derived by adding an electron to molecular oxygen and is suspected of having a widespread, albeit transitory, existence in nature. The elegant

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